The purpose of the 21st Century Community Learning Center (21st CCLC) program is to provide for the establishment or expansion of Community Learning Centers (Centers) to assist students from high-poverty and low-performing schools in meeting academic achievement standards in core subjects, provide out-of-school time programs to reinforce and complement the regular academic programs, and offer families of participating students opportunities for literacy and educational development. This report profiles data from the Colorado Department of Education's fifth and sixth cohorts of grantees for the 2012-2013 reporting year. The fifth cohort consists of 31 grantees affiliated with 69 Centers. The sixth cohort consists of 34 grantees associated with 60 centers. (author abstract)